In Jessica Chastain's latest movie, "Woman Walks Ahead," she continues her quest to get powerful female stories to the big screen. But to make things more challenging, this one is a Western."Woman Walks Ahead" follows the true story of Catherine Weldon, played by Chastain, a 1800s portrait painter from Brooklyn who travels out West to seek out Sitting Bull to paint him. But the two quickly build a friendship leading to Weldon assisting the legendary Native American leader and the Lakota people in their struggle over land rights.